报告题目：Bond Activation and Catalysis by Main Group Systems

报告人：Dr. Uwe Schneider

报告时间：2015年11月9日(星期一)，13:45-15:00

报告地点：上海市四平路1239号太阳成集团化学馆120室

About Dr. Uwe Schneider

Academic Experience:

— Sep 2011 ~ present: Lecturer,The University of Edinburgh

— Nov 2007 ~ Aug 2011: Assistant Professor (PI) – Apr 2009: tenure,The University of Tokyo

— Apr 2006 ~ Nov 2007: Group Leader (PI) [ERATO programme],The University of Tokyo

Education & Research Experience:

— Jan 2004 ~ Mar 2006: Postdoctoral Research Associate,The University of Tokyo

— Sep 2003: Examination of PhD Thesis, Institut de Recherche en Chimie Organique Fine (IRCOF), Rouen – France

— Chemistry studies at the Universities of Würzburg & Marburg – Germany & Lille & Lyon – France

Awards:

— Marie Curie Career Integration Award (2012)

— Thieme Chemistry Journal Award (2011)

— Global COE Overseas Lectureship Award (2010 & 2008)

About the lecture

The lecture on 9^thNov.will disclose data obtained in three complementary strands of Dr. Uwe Schneider’s current research, all focused on the development of novel (asymmetric) base, acid, and/or dual catalysts. In the lecture, bis(dialkylamino)cyclopropenylidenes(BAC’s), gallium(I) complexes and metal amides, as three kinds of catalysts which lead to unique reactions, will be discussed respectively. Chiral BAC, Uwe Schneider developed as an enantioselective catalyst, has resulted in highly asymmetric aza-Morita–Baylis–Hillman reactions at ambient temperature (up to 97%ee); gallium(I) complexes, with their both electron donor and acceptor properties, have been shown to be acidic, basic, or ambiphilic in a stoichiometric context, which displays different reaction possibilities from conventional consideration; As for metal amides, Uwe Schneider has developed the first sodium amide-catalyzed C–C bond formations between various imines and unbiased or functionalized olefins through a rare formal C(sp³)–H bond activation. All above will be involved in details in next Monday’s lecture.