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许茂桐，博士，特聘研究员，博士生导师 |
太阳成集团高等研究院、0638太阳集团 |
联系电话： |
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传真号码： 办公地址： |
+86-21-65981097 上海市四平路1239号太阳成集团工程馆213室 |
电子邮箱: |
maotongxu@tongji.edu.cn |
个人主页： |
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许茂桐，2016年本科毕业于多伦多大学化学系，随后继续在多伦多大学攻读硕士和博士学位（2016-2021），师从英国、加拿大皇家科学院院士Douglas W. Stephan教授。研究方向包含主族元素化学物的合成及其在小分子（一氧化碳、二氧化碳、氢气等）催化转化上的应用。截至目前，在Angew. Chem., J. Am. Chem. Soc.等学术期刊发表论文十余篇；并在多个知名国际会议中做学术汇报；入选2021年度上海领军人才（海外）青年项目，2023年入选国家级青年人才计划。
一、教育及工作经历
2022，特聘研究员，太阳成集团
2021，博士学位，多伦多大学
2018，硕士学位，多伦多大学
2016，学士学位，多伦多大学
二、研究方向：
主族元素化学（Main group Chemistry）
受阻路易斯酸碱对（Frustrated Lewis Pairs）
小分子活化和催化（Small-molecule Activation and Catalysis）
有机金属化学（Organometallics）
三、荣誉与奖励:
2020，国家优秀自费职工奖学金
2016，Collin H. Bayley Fellowship in Chemistry
2015，Canadian Society for Chemistry Silver Medal
四、科研项目:
2022，自然科学基金青年基金
2021，上海领军人才（海外）青年项目
五、研究论文：
1. Maotong Xu, Bastiaan Kooij, Tongtong Wang, Jack H. Lin, Zheng-wang Qu*, Stefan Grimme, Douglas W. Stephan*, Facile synthesis of cyanide and isocyanides from CO, Angew. Chem. Int. Ed. 2021, 60, 16965-16969
2. Maotong Xu, Zheng-wang Qu*, Stefan Grimme, Douglas W. Stephan*, Lithium Dicyclohexylamide in Transition-Metal-Free Fischer-Tropsch Chemistry, J. Am. Chem. Soc. 2021, 143, 634-638
3. Maotong Xu§, Tongtong Wang§, Zheng-wang Qu*, Stefan Grimme, Douglas W. Stephan*, Reactions of a dilithiomethane with CO and N2O: An avenue to an anionic ketene and a hexafunctionalized benzene, Angew. Chem. Int. Ed. 2021, 60, 25281-25285 共一
4. Maotong Xu, Andrew R. Jupp, Maegan S. E. Ong, Katherine I. Burton, Saurabh S. Chitnis, Douglas W. Stephan*, Synthesis of Urea Derivatives from CO2 and Silylamines, Angew. Chem. Int. Ed. 2019, 58, 5707-5711
5. Maotong Xu, Andrew R. Jupp, Douglas W. Stephan*, Acyl‐Phosphide Anions via an Intermediate with Carbene Character: Reactions of K[PtBu2] and CO, Angew. Chem. Int. Ed. 2019, 58, 3548-3552
6. Maotong Xu, Andrew R. Jupp, Zheng‐Wang Qu, Douglas W. Stephan*, Alkali Metal Species in the Reversible Activation of H2, Angew. Chem. Int. Ed. 2018, 57, 11050-11054
7. Maotong Xu, Andrew R. Jupp, Douglas W. Stephan*, Stoichiometric Reactions of CO2 and Indium‐Silylamides and Catalytic Synthesis of Ureas, Angew. Chem. Int. Ed. 2017, 56, 14277-14281
8. Maotong Xu, Josephine Possart, Alexander E. Waked, Julie Roy, Werner Uhl*, Douglas W. Stephan*, Halogenated triphenylgallium and indium in frustrated Lewis pair activations and hydrogenation catalysis, Phil. Trans A. 2017, 2101, 375, 1-12
9. Tongtong Wang§, Maotong Xu§, Andrew R. Jupp, Zheng-wang Qu*, Stefan Grimme, Douglas W. Stephan*, Selective catalytic Frustrated Lewis Pair Hydrogenation of CO2 in the Presence of Silylhalides, Angew. Chem. Int. Ed. 2021, 60, 25771-25775 共一
10. Tongtong Wang, Maotong Xu, Andrew R. Jupp, Shi-Ming Chen, Zheng-Wang Qu*, Stefan Grimme, Douglas W. Stephan*, Frustrated Lewis pair catalyzed hydrodehalogenation of benzyl-halides, Chem. Commun. 2022, 58, 1175-1178
11. Tongtong Wang, Maotong Xu, Andrew R. Jupp, Zheng-Wang Qu*, Stefan Grimme, Douglas W. Stephan*, Steric Influence on Reactions of Benzyl Potassium Species with CO, Chem. Asian J. 2021, 16, 3640-3644
12. Kevin M. Szkop, Andrew R. Jupp, Hlib Razumkov, Maotong Xu, Douglas W. Stephan*, Chem. Eur. J. 2019, 25, 10084 -10087
13. Trevor Janes, Maotong Xu, Datong Song*, Synthesis and reactivity of Li and TaMe3 complexes supported by N, N′-bis(2,6-diisopropylphenyl)-o-phenylenediamido ligands, Dalton Trans. 2016, 45, 10672-10680
14. Yanxin Yang, Maotong Xu, Datong Song*, Organocatalysts with carbon-centered activity for CO2 reduction with boranes, Chem. Commun. 2015, 51, 11293-11296
