个人简介
费泓涵于2007年7月在复旦大学化学系获理学学士学位,并于同年赴美国加州大学圣克鲁斯分校化学与生化学院攻读博士学位,师从材料化学家Scott R. J. Oliver教授,从事阳离子型杂化晶格矩阵合成与环境领域的应用研究, 并于2012年8月获得博士学位。同年起在加州大学圣地亚哥分校化学与生化学院进行博士后研究工作,师从无机化学家Seth M. Cohen教授,致力于金属有机骨架的修饰与非均相催化领域的研究。2015年3月受聘于太阳成集团高等研究院,授特聘研究员,并于2016年5月起签约0638太阳集团,任特聘教授、博士生导师。
一、研究方向:
1.阳离子型二维无机材料的构筑与插/剥层化学及其光、电性能研究
2.金属有机框架(MOF)的修饰及其对CO2捕获和转化功能研究
二、荣誉与奖励
1.Ludo Frevel晶体学奖(国际衍射数据中心,ICDD)
2.上海市青年科技项目启明星
3.Chancellor's Dissertation Year Fellowship (加州大学圣克鲁斯分校)
4.Doctoral Sabbatical Fellowship(加州大学圣克鲁斯分校)
三、主要科研项目:
1.主持国家自然科学基金面上项目:基于低维金属卤族结构单元的金属有机框架的合成及其本征宽谱发光性质研究 (2020-2023)
2.主持国家自然科学基金面上项目:基于有机磺酸配体的三维多孔金属有机框架的合成及其对CO2捕获和转化功能研究 (2018-2021)
3.主持上海市青年科技启明星项目:阳离子型卤化铅结构单元的构建和光化学研究(2020-2023)
4.主持国家自然科学基金青年项目:光敏金属有机框架材料薄膜的组装和光电转换(2016-2018)(已结题)
四、学术成果
在博士(UC Santa Cruz, 2007~2012)和博士后(UC San Diego, 2012~2015)期间发表论文20余篇,其中以第一作者在国际著名化学和材料学期刊发表论文18篇,包括发表在J. Am. Chem. Soc.6篇与Angew. Chem Int. Ed.1篇。
在太阳成集团建立独立课题组以来(2015~至今),以通讯作者在国际著名化学和材料学期刊发表论文20余篇, 其中发表在Nat. Catal.1篇、Angew. Chem. Int. Ed.3篇、Adv. Mater.1篇、以及Chem. Sci.、ACS. Catal.、Chem. Mater.等多篇。
总共发表论文50余篇,他引累计近3000次,多篇论文被选为“封面文章”、“ESI高被引论文”和“The Most Read论文”。研究成果曾被美国国家自然科学基金(NSF)官网报道,曾参与多项美国能源部(DOE)和美国国家自然科学基金(NSF)资助的研究课题,现作为课题负责人主持国家自然科学基金两项。
代表性论著:
2020:
25. Xueling Song, Guangfeng Wei, Jiao Sun, Chengdong Peng, Jinlin Yin, Xu Zhang, Yilin Jiang,Honghan Fei*“Overall Photocatalytic Water Splitting by an Organolead Iodide Crystalline Material”Nat. Catal.,2020, accepted in press.
24. Xueling Song, Chengdong Peng, Xiaoxiang Xu, Jinlin Yin,Honghan Fei*Efficient, Broadband Self-Trapped White-Light Emission from Haloplumbate-Based Metal-Organic Frameworks”Chem. Commun., 2020, 56, 10078-10081.
23. Guiyang Zhang, Jinlin Yin, Xueling Song,Honghan Fei*“A Moisture-Stable Organosulfonate-Based Metal-Organic Framework with Intrinsic Self-Trapped White-Light Emission”Chem. Commun.,2020, 56, 1325-1328. (Selected as Front Cover) (HOT article)
22. Yilin Jiang, Xu Zhang,Honghan Fei*“N-Heterocyclic Carbene-Functionalized Metal-Organic Frameworks for Chemical Fixation of CO2”Dalton Trans,2020, 49, 6458-6552.(Invited Review)
21. Xiaoxiang Xu*, Yinghao Xie,Honghan Fei,Shu Jin, Yinlin Shao“Ge-Modified GaN-ZnO Wurtzite Solid Solutions with High Zn Content for Efficient Photocatalytic H2 Evolution from Water under Visible Light Illumination”Inorg. Chem. Front.,2020, 7, 3443-3447.
2019:
20. Chengdong Peng, Xueling Song, Jinlin Yin, Guiyang Zhang, Honghan Fei*“Intrinsic White-Light-Emitting Metal-Organic Frameworks with Structurally Deformable Secondary Building Units” Angew. Chem. Int. Ed., 2019, 58, 7818-7822.
19. Xu Zhang, Jiao Sun, Guangfeng Wei*, Zhipan Liu, Huimin Yang, Kaimin Wang,Honghan Fei*“In-situ Generation of AnN-Heterocyclic Carbene-Functionalized Metal-Organic Framework via Postsynthetic Ligand Exchange for Efficient and Selective Hydrosilylation of CO2”Angew. Chem. Int. Ed., 2019, 58, 2844-2849.
18. Jinlin Yin, Huimin Yang,Honghan Fei*“Robust, Cationic Lead Halide Layered Materials with Efficient Broadband White-Light Emission”Chem. Mater.,2019, 31, 3909-3916.
17. Jinlin Yin, Guiyang Zhang, Chengdong Peng,Honghan Fei*“An Ultrastable Metal-Organic Material Emits Efficient and Broadband Bluish White-Light Emission for Luminescent Thermometers”Chem. Commun.,2019, 55, 1702-1705. (Selected as Front Cover)
16. Xu Zhang, Yilin Jiang,Honghan Fei*“UiO-Type Metal-Organic Frameworks with NHC or Metal-NHC Functionalities for N-Methylation Using CO2 as the Carbon Source”Chem. Commun.,2019, 55, 11928-11931.
15. Huimin Yang, Jinlin Yin, Xiaoxiang Xu*,Honghan Fei*“Enhanced Intrinsic White-Light Emission Upon Near-UV Excitation by Crystal Engineering of Cationic Lead Bromide Layered Materials”J. Mater. Chem. C,2019, 7, accepted in press.
14. Guiyang Zhang,Honghan Fei*“Synthesis and Applications of Porous Organosulfonate-Based Metal-Organic Frameworks”Topics in Current Chemistry,2019,accepted in press. (Invited Review)
13. Ana R. K. Chatenever, Louis R. Warne, Joe E. Matsuoka, Stanley J. Wang, Eric W. Reinheimer, Pierre LeMagueres,Honghan Fei,Xueling Song, Scott R. J. Oliver, “Isomorphous Lanthanide Metal-Organic Frameworks Based on Biphenyldicarboxylate: Synthesis, Structure, and Photoluminescent Properties”Cryst. Growth Des.,2019, 19, 4854-4859.
2018:
12. Jina Hao, Xiaoyu Xu,Honghan Fei*, Liangchun Li*, Bing Yan* “Functionalization of Metal-Organic Frameworks for Photoactive Materials.”Adv. Mater.,2018, 30, 1705634. (Invited Review)
11. Chengdong Peng, Zewen Zhuang, Huimin Yang, Guiyang Zhang,Honghan Fei*“Ultrastable, Cationic Three-Dimensional Lead Bromide Frameworks that Intrinsically Emits Broadband White-Light.”Chem. Sci.,2018, 9, 1627-1633.
10. Guiyang Zhang, Huimin Yang,Honghan Fei*“Unusual Missing Linkers in an Organosulfonate-Based Primitive-Cubic(pcu)-Type Metal-Organic Framework for CO2Capture and Conversion Under Ambient Condition.”ACS Catal.,2018, 8, 2519-2525.
9. Ben Johnson, Asamanjoy Bhunia,Honghan Fei, Seth M. Cohen, Sascha Ott* “Development of a UiO-type Thin Film Electrocatalysis Platform with Redox Active Linkers.”J. Am. Chem. Soc.,2018, 140, 2985-2994.
8. Huimin Yang, Xu Zhang, Guiyang Zhang,Honghan Fei*“An Alkaline-Resistant Ag(I)-Anchored Pyrazolate-Based Metal-Organic Framework for Chemical CO2Fixation”Chem. Commun.,2018, 54, 4469-4472.
7. Xueling Song, Chengdong Peng,Honghan Fei*“Enhanced Electrocatalytic Oxygen Evolution by Exfoliation of a Metal-Organic Framework Containing Cationic One-Dimensional [Co4(OH)2]6+ Chains”ACS Appl. Energy Mater.,2018, 1, 2446-2451.
6. Jinlin Yin,Honghan Fei*“Cationic Two-Dimensional Inorganic Network of Antimony Oxide Hydroxide for Lewis Acid Catalysis.”Dalton Trans.,2018, 47, 4054-4058.
2017:
5. Zewen Zhuang, Chengdong Peng, Guiyang Zhang, Huimin Yang, Jinlin Yin,Honghan Fei*“Intrinsic Broadband White-Light Emission from Ultrastable, Cationic Lead Halide Layered Materials.”Angew. Chem. Int. Ed.,2017, 56, 14411-14416.
4. Huimin Yang,Honghan Fei*“Exfoliation of a Two-Dimensional Cationic Inorganic Network as a New Paradigm for High-Capacity Cr(VI)-Anion Capture.”Chem. Commun.,2017,53, 7064-7067.
3. Guiyang Zhang,Honghan Fei*“Missing Metal-Linker Connectivities in a Robust 3-D Sulfonate-Based Metal-Organic Framework for Enhanced Proton Conductivity.”Chem. Commun.,2017,53, 4156-4159.
2. Huimin Yang,Honghan Fei*“A Generic and Facile Strategy to Fabricate Metal-Organic Framework Films on TiO2 Substrates for Photocatalysis.”Dalton Trans.,2017,46, 2751-2755.
2016:
1. Guiyang Zhang, Guangfeng Wei, Zhipan Liu, Scott R. J. Oliver*,Honghan Fei*“A Robust Sulfonate-Based Metal-Organic Framework with Permanent Porosity for Effcient CO2 Capture and Conversion.” Chem. Mater., 2016, 28, 6276-6281.
Before Tongji (Ph.D. and PostDocs)
Honghan Fei, Seth M. Cohen* “Metalation of a Thiocatechol-Functionalized Zr(IV)-based Metal-Organic Framework for Selective C-H Functionalization.”J. Am. Chem. Soc.,2015,137, 2191-2194.
Honghan Fei, JaeWook Shin, Ying S. Meng, Mario Adelhardt, Jorg Sutter, Karsten Meyer, Seth M. Cohen* “Reusable Oxidation Catalysis Using Metal-Monocatecholato Species in a Robust Metal-Organic Framework.”J. Am. Chem. Soc.,2014,136, 4965-4973.
Sonja Pullen‡,Honghan Fei‡, Andreas Orthaber, Seth M. Cohen*, Sascha Ott* “Enhanced Photochemical Hydrogen Production by a Molecular Diiron Catalyst Incorporated into a Metal-Organic Framework.”J. Am. Chem. Soc.,2013,135, 16997-17003(‡equal contribution).
Honghan Fei, Catherine H. Pham, Scott R. J. Oliver* “Anion Exchange of the Cationic Layered Material [Pb2F2]2+.”J. Am. Chem. Soc.,2012,134, 10729-10732.
Honghan Fei, Marc R. Bresler, Scott R. J. Oliver* “A New Paradigm for Anion Trapping in High Capacity and Selectivity: Crystal-to-Crystal Transformation of Cationic Materials.”J. Am. Chem. Soc.,2011,133, 11110-11113.
Honghan Fei, David L. Rogow, Scott R. J. Oliver* “Reversible Anion Exchange and Catalytic Properties of Two Cationic Metal-Organic Frameworks Based on Cu(I) and Ag(I)” J. Am. Chem. Soc.,2010, 132, 7202-7209.
Honghan Fei, Scott R. J. Oliver* “Copper Hydroxide Ethanedisulfonate: A Cationic Inorganic Layered Material for High-Capacity Anion Exchange.”Angew. Chem. Int. Ed.,2011,50, 9066-9070.
Honghan Fei, Matthew D. Sampson, Yeob Lee; Clifford P. Kubiak*; Seth M. Cohen* “Photocatalytic CO2 Reduction to Formate Using a Mn(I) Molecular Catalyst in a Robust Metal-Organic Framework.”Inorg. Chem.,2015,54, 6821-6828.
Honghan Fei, Sonja Pullen, Andreas Wagner, Sascha Ott*; Seth M. Cohen* “Functionalization of Robust Zr(IV)-based Metal-Organic Framework Films via a Postsynthetic Ligand Exchange.”Chem. Commun.,2015,51, 66-69.
Honghan Fei, Seth M. Cohen* “Robust, Catalytic Metal-Organic Framework with Open 2,2'-Bipyridine Sites.”Chem. Commun.,2014, 50, 4810-4812.
Honghan Fei, John F. Cahill, Kimberly A. Prather, Seth M. Cohen* “Tandem Postsynthetic Metal Ion and Ligand Exchange in Zeolitic Imidazolate Frameworks.”Inorg. Chem.,2013,52, 4011-4016.
Honghan Fei, Cari S. Han, Jeremy, C. Robins, Scott R. J. Oliver* “A Cationic Metal-Organic Solid Solution Based on Co(II) and Zn(II) for Chromate Trapping”Chem. Mater.,2013,25, 647-652.
Honghan Fei, Cari S. Han, Scott R. J. Oliver* “A Cationic Antimonite Chain Tempalted by Sulfate [Sb6O74+][(SO42-)2].” Inorg. Chem.,2012,51, 8655-8657.
Honghan Fei, Yuchen Yang, David L. Rogow, Xiaojuan Fan, Scott R. J. Oliver* “Polymer-Templated Nanospider TiO2 Thin Films for Effcient Photoelectrochemical Water Splitting.” ACS Appl. Mater. Interface,2010,2, 974-979.
Honghan Fei, Latisha Paw U, David L. Rogow, Marc R. Bresler, Yashar A. Abdollahian, Scott R. J. Oliver* “Synthesis, Characterization, and Catalytic Application of a Cationic Metal-Organic Framework: Ag2(4,4'-bipy)2(O3SCH2CH2SO3)”Chem. Mater.,2010,22, 2027-2032.